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From Forbes List

We can see that the first from Quebec is Paul Desmarais. When you see that Jean Coutu is worth 1.5 billion, it's make a new sense to his publicity. I now understand why the young hockey player wanted to be Jean Coutu ! And the Cirque Du Soleil founder is worth 1.4B. You can also make lot of money by selling cheap cheese and cheap frosted juice, pizza, french fries etc...

1	Kenneth Thomson & family	Canada	82	19,6	Canada
2	Galen Weston & family	Canada	65	8,4	Canada
3	James, Arthur & John Irving	Canada		5,5	Canada
4	Jeffrey Skoll	Canada	41	5,0	United States
5	Paul Desmarais	Canada	79	3,8	Canada
6	Bernard (Barry) Sherman	Canada	64	3,7	Canada
7	Jim Pattison	Canada	77	3,5	Canada
8	Robert Miller	Canada	60	3,0	Canada
9	Edward Rogers	Canada	72	3,0	Canada
10	Charles Bronfman	Canada	74	2,7	Canada
11	Emanuele (Lino) Saputo & family	Canada	69	2,4	Canada
12	Wallace McCain	Canada	76	2,3	Canada
13	Michael Lee-Chin	Canada	55	2,1	Canada
14	Daryl Katz	Canada	44	1,6	Canada
15	Alexander Shnaider	Canada	37	1,6	Canada
16	Jean Coutu	Canada	78	1,5	Canada
17	Stephen Jarislowsky	Canada	80	1,5	Canada
18	N Murray Edwards	Canada	46	1,4	Canada
19	Guy Laliberte	Canada	46	1,4	Canada
20	David Cheriton	Canada		1,0	United States
Average :				3,8
Total :				75,0

This above comes from Forbes World richest man, so it should be the samething for canada. I only found one article that list the richest canadian but it's for 2004, and it's reflect the one above (not a lot of changes).
(Celine Dion isn't in :D but Keanu Reeves "$336 million" is in the spot 100.)
Canadian Business Top100 2003-2004 richest man.